SOOC. I was helping Ork with a photoshoot, and trying out a new lighting rig at the same time. The key came from camera right, a 580EXII through a Lumiquest III from top right, and a 430EXII with a dome diffuser from bottom right. The rim light was provided by a bare 430EX on a VAL with a monopod.
I shot this in RAW. Funnily enough the look I got from the camera was better than I got with Bibble, my RAW editing software. So I extracted the full-size JPEG out of the RAW and posted that here without any editing :)