I've been wanting to light an image like this for a while. This is not a Photoshop creation, but as close to straight out of the camera as I get. It is a duotone (Black and Pantone 157 C), though.
Alien Bee B800 in a vertical stripbox behind model and to camera left. No fill, black seamless backdrop. Skyport trigger.
Model: Cynthia Muse (Model Mayhem #1494568)