Spider-man from "Classic Clashes Spider-man vs Abomination". This is the same Spider-man from SMC 12, which is also the most sought after Spidey action figure amongst collectors. Why? Simply because of its exceptional sculpt and articulation.
Green Goblin from Toybiz Marvel Legends Onslaught series. This, I feel, it the best rendition of this character so far... Yeah, cone-headed Goblin from the movies is crap to me. The classic one has always come with a rubber mask and pumpkin bombs with a bat glider. Nothing silly about such a halloween costume, too bad Sam Raimi couldn't pull it off.